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1 article(s) from Belov, Sergey S

Solid-phase-supported synthesis of morpholinoglycine oligonucleotide mimics

Tatyana V. Abramova,
Sergey S. Belov,
Yulia V. Tarasenko and
Vladimir N. Silnikov

Beilstein J. Org. Chem. 2014, 10, 1151–1158, doi:10.3762/bjoc.10.115

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Figure 1: Morpholinoglycine oligomers (A) and protected monomers 1a–e (B) for their synthesis.

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Figure 2: Dangling residues of MorGly oligomers synthesized by solid phase supported (A) and liquid phase syn...

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Figure 3: Cleavage of MorGly oligonucleotide mimics from solid support and deprotection of nucleobases by aqu...

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Scheme 1: Synthesis of Boc-protected 2-aminomethylmorpholino nucleosides: i) di-tert-butyl dicarbonate ((Boc)₂...

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Scheme 2: Loading of the Boc-Gly-PAM resin with the morpholino nucleosides 5a,d,e: i) Dimethyl oxalate, TEA, ...

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Figure 4: MorGly homopentamers containing adenine, uracil, and thymine nucleobases.

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Published 20 May 2014

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